长江河口涨、落潮槽内的沙波地貌和输移特征   总被引：3，自引：0，他引：3       下载免费PDF全文

王永红  沈焕庭  李九发  茅志昌 《海洋与湖沼》2011,42(2):330-336

涨、落潮槽是河口区的重要地貌单元,槽内由于不同的优势流作用而表现出不同的泥沙运移特征。沙波是底沙输移的表现,因此研究槽内的沙波特征对于涨、落潮槽的水动力和沉积地貌研究有重要的意义。本文依据现场声纳观测、测深仪测深、表层取样和现场水动力观测等方法获得河槽床面沙波和水动力资料,对沙波的几何形态、波高和全潮周期的迁移距离进行...  相似文献   

Molecular weight and chemical reactivity of dissolved trace metals (Cd,Cu, Ni) in surface waters from the Mississippi River to Gulf of Mexico     

Liang-Saw Wen  Peter H. Santschi  Kent W. Warnken  William Davison  Hao Zhang  Hsiu-Ping Li  Kuo-Tung Jiann 《Estuarine, Coastal and Shelf Science》2011

It is generally assumed that estuarine mixing is continuous for metals from terrestrial sources, gradually decreasing towards the open ocean endmember. Here we show that, chemical reactivity, determined by ion exchange method, and molecular weight distributions, obtained using cross-flow ultrafiltration, of dissolved Cd, Cu, and Ni in the surface waters of the Gulf of Mexico varied systematically across the estuarine mixing zone of the Mississippi River. Most size or chemical affinity fractions of dissolved metals (<0.4 μm) were linearly related to salinity (10.8–36.6), suggesting that the distribution of these elements was mainly controlled by continuous mixing processes. Dissolved concentrations across the salinity gradient ranged for Cd: 87–187 pM; Cu: 1.4–18.3 nM; and Ni: 2.6–18.8 nM, with highest values near the Mississippi river mouth, and lowest concentrations in a warm core ring in the Gulf of Mexico. Dissolved Cd was mostly present as a truly dissolved (<10 kDa, 97 ± 1%) and cationic fraction (Chelex-100 extractable, 94 ± 4%). A novel observation across the estuarine mixing zone was that colloidal metal concentrations were identical to either inert (for Cu, Ni) or AMPG-labile anionic (Cu, Cd) fractions. The difference in behavior between Cu and the other two metals might indicate differences in the biopolymeric nature of the metal–organic chelates. In particular, the anionic-organic Cd fractions accounted for just 3 ± 1%, on average. However, for Cu, it was 24 ± 4%, and for Ni, it was 9 ± 6%. The fractions of the total dissolved metal fractions that were “inert” averaged 31 ± 10% for Cu and 29 ± 12% for Ni. Small but noticeable amounts (6 ± 3%) of dissolved inert Cd fractions were also present. Apparent non-local transport processes, likely associated with cross-shelf sediment resuspension processes, could have been responsible for the relatively high concentrations of ‘inert’ and ‘anionic’ metal fractions in high salinity coastal waters, and accounting for the persistence of metals bound to humic substances in the Gulf of Mexico.  相似文献   

Metal binding by humic acids in recent sediments from the SW Iberian coastal area     

J.M. De la Rosa  M. SantosM.F. Araújo 《Estuarine, Coastal and Shelf Science》2011

The concentrations of Cu, Zn, Cr, Ni, Pb, As, Mn and Co were determined by Inductively Coupled Plasma–Mass Spectrometry both in recent sediments from different locations of the Huelva littoral (SW Iberian Peninsula) and in their humic acid (HA) fractions in order to evaluate distribution and binding capacity of those trace elements to HAs. In addition, elemental composition (C, N, S) and δ¹³C values were determined to appraise the sources of organic matter in the area. This study involved the comparison of selected samples taken from different environments including the estuary of the Guadiana River, the main fluvial system of the region, the Tinto and Odiel estuary system and the proximal shelf. Significant positive correlations were found among Cu, Zn, As and Pb in bulk sediments, suggesting a common origin of all of those elements: the mining activities and pyrite deposits located hinterland. On the other hand, results for Cr, Co and Ni pointed to the basic rocks from the low basin of the Guadiana River as their main source. Elemental (C, N) and isotopic (δ¹³C) composition of sediments indicated a significant contribution of autochthonous plankton in coastal shelf sediments, whereas estuarine and riverine sediments showed a major contribution of terrestrial biomass. Geochemical values for their corresponding HAs suggested a greater terrestrial contribution in the sedimentary OM of the coastal shelf sediments than in bulk sediments, which evidenced the influence of coastal currents and sediment fluxes. Humic acids sequester considerable amounts of Cu and Zn contributing to reduce the bioavailability of these contaminants.  相似文献   

Temporal and spatial variability of dissolved organic carbon concentration in the Xijiang River, South China     

Zhen Tao  Quanzhou Gao  Wenping Guo  Zhengang Wang  Yongling Zhang  Chenji Xie  Xiakun Huang  Hongwei Zhong 《山地科学学报》2011,8(5):694-703

A whole year analysis of riverine dissolved organic carbon (DOC) concentrations in the Xijiang River (XJR), South China, showed that the mean riverine DOC concentration (1.24 mg L-1) in the XJR was notably lower than the averaged value (5.75 mg L-1) of the global riverine DOC concentration in several major rivers. There is an inconspicuous monthly fluctuation of the DOC signal in the XJR, but on a semi-yearly time scale, however, the riverine DOC concentration had significant difference between hydrological...  相似文献   

Determination of Ga,Ge, Mo,Ag, Cd,In, Sn,Sb, W,Tl and Bi in USGS Whole‐Rock Reference Materials by Standard Addition ICP‐MS          下载免费PDF全文

Richard M. Gaschnig  Roberta L. Rudnick  William F. McDonough 《Geostandards and Geoanalytical Research》2015,39(3):371-379

A procedure for determining a wide range of chalcophile and siderophile elements in typical crustal rocks using standard addition and ICP‐SFMS (inductively coupled plasma sector field mass spectrometry) is presented. New results for Ga, Ge, Mo, Ag, Cd, In, Sn, Sb, W, Tl and Bi abundances in USGS whole‐rock reference materials AGV‐2, BHVO‐1, BIR‐1, G‐2, GSP‐1 and W‐2 are reported using this analytical procedure. Intermediate precision of means based on multiple dissolved aliquots of each USGS reference material was 10% RSD or better for Ga, Ge, In and Sn in all, and similarly good for Ag, Cd, Sb, Tl and Bi in most reference materials. Poorer intermediate precision of Mo and W measurements in several reference materials is probably due to higher analytical blanks on these elements and powder heterogeneity due to a sulfide‐related nugget effect in the specific case of Mo in GSP‐1. Results for all elements fell within the range of available published data with the exception of Ag, which yielded systematically higher concentrations than found in the literature for five of the six reference materials, likely reflecting interference from unresolved polyatomic species.  相似文献   

Mass Fractions of S,Cu, Se,Mo, Ag,Cd, In,Te, Ba,Sm, W,Tl and Bi in Geological Reference Materials and Selected Carbonaceous Chondrites Determined by Isotope Dilution ICP‐MS          下载免费PDF全文

Zaicong Wang  Harry Becker  Frank Wombacher 《Geostandards and Geoanalytical Research》2015,39(2):185-208

Mass fractions of S, Cu, Se, Mo, Ag, Cd, In, Te, Ba, Sm, W and Tl were determined by isotope dilution sector field ICP‐MS in the same sample aliquot of reference materials using HF‐HNO₃ digestion in PFA beakers in pressure bombs and glassy carbon vessels in a high‐pressure asher (HPA‐S) for comparison. Additionally, Bi was determined by internal standardisation relative to Tl. Because isobaric and oxide interferences pose problems for many of these elements, efficient chromatographic separation methods in combination with an Aridus desolvator were employed to minimise interference effects. Repeated digestion and measurement of geological reference materials (BHVO‐1, BHVO‐2, SCo‐1, MAG‐1, MRG‐1 and UB‐N) gave results with < 5% relative intermediate precision (1s) for most elements, except Bi. Replicates of NIST SRM 612 glass digested on a hot plate were analysed by the same methods, and the results agree with reference values mostly within 2% relative deviation. Data for the carbonaceous chondrites Allende, Murchison, Orgueil and Ivuna are also reported. Digestion in a HPA‐S was as efficient as in pressure bombs, but some elements displayed higher blank levels following HPA‐S treatment. Pressure bomb digestion yielded precise data for volatile S, Se and Te, but may result in high blanks for W.  相似文献   

江西大湖塘超大型钨矿初始岩浆流体出溶——来自似伟晶岩壳的记录   总被引：1，自引：0，他引：1  

张智宇  侯增谦  彭花明  朱晓强  潘小菲  叶泽宇 《地质通报》2015,34(203):487-500

江西大湖塘地区是江南造山带中段九岭矿集区内近年查明的世界级超大型钨矿产地,白钨矿体主要呈细脉浸染状缓倾于中粗粒黑云母花岗闪长岩中。位于区内一矿带的成矿母岩顶部发育完好的似伟晶岩壳,壳层的组构特征明显,由母岩向含矿围岩,依次为似斑状黑云母花岗岩→长英质细晶岩→石英长石似伟晶岩→长石石英似伟晶岩→含白钨矿黑云母花岗闪长岩。壳内石英的阴极发光岩相学研究显示,石英巨晶、斑晶、基质和石英脉大多经历了早阶段主晶石英,中阶段扩散交代石英和晚阶段渗滤充填石英3个生长阶段。微量元素研究表明,早阶段石英的生长是一个流体加速沉淀的过程,中阶段和晚阶段流体对主晶石英均有叠加改造,其微量元素呈降低趋势。各类石英均表现为富碱金属元素、中高温（≥483℃）、低Li/Al（0.01~0.50,大多小于0.24）的地球化学特征,反映了成矿流体为岩浆水来源,石英的生长具有岩浆—热液过渡性质。综合研究表明,大湖塘一矿带似伟晶岩壳是初始含矿岩浆流体出溶的产物,其形成过程中动态的物理化学条件促进了成矿元素W由母岩向围岩搬运富集。  相似文献   

卵石地层的特殊性及其对基坑支护的影响分析     

刘伍  李海明 《城市地质》2015,(Z2)

主要从卵石地层的特征分类、特殊结构及场内施工条件3个方面,对基坑支护结构选型及施工工艺选择进行深入、系统的分析论证,力求使在卵石地层中的基坑支护设计方案更科学、经济,使施工方法、工艺更具可操作性。  相似文献   

Kinematics of syn-tectonic unconformities and implications for the tectonic evolution of the Hala'alat Mountains at the northwestern margin of the Junggar Basin,Central Asian Orogenic Belt     

Delong Ma  Dengfa He  Di Li  Jieyun Tang  Zheng Liu 《地学前缘(英文版)》2015,6(2):247-264

The Hala’alat Mountains are located at the transition between the West Junggar and the Junggar Basin.In this area,rocks are Carboniferous,with younger strata above them that have been identified through well data and high-resolution 3D seismic profiles.Among these strata,seven unconformities are observed and distributed at the bases of:the Permian Jiamuhe Formation,the Permian Fengcheng Formation,the Triassic Baikouquan Formation,the Jurassic Badaowan Formation,the Jurassic Xishanyao Formation,the Cretaceous Tugulu Group and the Paleogene.On the basis of balanced sections,these unconformities are determined to have been formed by erosion of uplifts or rotated fault blocks primarily during the Mesozoic and Cenozoic.In conjunction with the currently understood tectonic background of the surrounding areas,the following conclusions are proposed:the unconformities at the bases of the Permian Jiamuhe and Fengcheng formations are most likely related to the subduction and closure of the Junggar Ocean during the late Carboniferous-early Permian;the unconformities at the bases of the Triassic Baikouquan and Jurassic Badaowan formations are closely related to the late Permian-Triassic Durbut sinistral slip fault;the unconformities at the bases of the middle Jurassic Xishanyao Formation and Cretaceous Tugulu Group may be related to reactivation of the Durbut dextral slip fault in the late Jurassic-early Cretaceous,and the unconformity that gives rise to the widely observed absence of the upper Cretaceous in the northern Junggar Basin may be closely related to large scale uplift.All of these geological phenomena indicate that the West Junggar was not calm in the Mesozoic and Cenozoic and that it experienced at least four periods of tectonic movement.  相似文献   

Late Jurassic-Early Cretaceous Northern Qaidam Basin, NW China: Implications for the earliest Cretaceous intracontinental tectonism   总被引：4，自引：0，他引：4  

Lei Wu  Ancheng Xiao  Liqun WangZhongyan Shen  Suping ZhouYuanzhong Chen  Liang Wang  Dong LiuJunya Guan 《Cretaceous Research》2011,32(4):552-564

Formation of Mesozoic western China, which was dominated by tectonic amalgamation along its southern margin and associated intracontinental tectonisms, holds a key for interpreting the succedent Cenozoic evolution. This paper presents new data including lithology, sedimentary facies, stratigraphic contact, seismic interpretation and paleo-structures within the Upper Jurassic-Lower Cretaceous strata in the northern Qaidam Basin, NW China. These data all account for a contractional tectonic deformation in the earliest Cretaceous. The South Qilian Shan, according to the sedimentary features and provenance analysis, reactivated and exhumated during the deformation, controlling the deposition of the Lower Cretaceous sequences. A simplified model for the Late Jurassic-Early Cretaceous paleogeography and tectonics of the northern Qaidam Basin is accordingly proposed. The results also support a ∼25° clockwise rotation of the Qaidam Basin since the Early Cretaceous and a more accurate Mesozoic evolution process for the basin. This earliest Cretaceous deformation, associated with the reactivation of the South Qilian Shan at the time, are part of the intracontinental tectonisms in central Asia during the Mesozoic, and probably driven by both the closure of the Mongol-Okhostk Ocean to the north and the collision of the Lhasa and the Qiangtang blocks to the south.  相似文献